Aryl Annulation of Cyclic Ketones via a Magnesium Carbometalation—6-π-Electrocyclization Protocol.
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چکیده
منابع مشابه
Direct β-functionalization of cyclic ketones with aryl ketones via the merger of photoredox and organocatalysis.
The direct β-coupling of cyclic ketones with aryl ketones has been achieved via the synergistic combination of photoredox catalysis and organocatalysis. Diaryl oxymethyl or aryl-alkyl oxymethyl radicals, transiently generated via single-electron reduction of ketone precursors, readily merge with β-enaminyl radical species, generated by photon-induced enamine oxidation, to produce γ-hydroxyketon...
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ژورنال
عنوان ژورنال: ChemInform
سال: 2005
ISSN: 0931-7597,1522-2667
DOI: 10.1002/chin.200529044